高效液相色谱法同时测定食用油中7种抗氧化剂的方法研究

本研究利用高效液相色谱同时测定食用油中没食子酸丙酯(PG)、没食子酸月桂酯(DG)、没食子酸辛酯(OG)、叔丁基对苯二酚(TBHQ)、叔丁基对羟基茴香醚(BHA)、2,6-二叔丁基对甲基苯酚(BHT)、2,6-二叔丁基-4-羟甲基苯酚(Ionox-100)7种抗氧化剂的测定方法,样品中的抗氧化剂经正己烷溶解、乙腈萃取后,经C18柱分离,乙腈-1.5%乙酸溶液体系为流动相进行梯度洗脱,紫外检测器检测,外标法定量。选择线性范围在1~100mg/L,结果表明7种抗氧化剂呈良好的线性关系,相关系数r大于0.999,方法的测定低限为0.8~2.0mg/kg,回收率在89.3%~110.1%,变异系数在1.5%~4.9%。该方法准确、快速、重现性好,可用于大批量食用油检测中7种抗氧化剂的定量分析。     

严寒地区高速铁路混凝土基床聚氨酯保温特性试验研究

基于严寒区京沈客专朝阳试验段路基基床的温度监测资料分析,研究不同厚度聚氨酯保温板对高速铁路路基混凝土基床温度变化特性影响.测试结果表明:①铺设聚氨酯保温板能够有效阻断严寒区环境与路基基床间的热量传递,保温效果与板厚相关;②地温大多数时间呈阳高阴低现象,同时阴、阳坡路基温差波动幅度随埋深逐渐减小;③基床表层阴、阳面各测点的温度变化起始时间一致,而阴面的冻结时间比阳面晚一个月.由此表明,保温板能够有效降低环境与混凝土道床之间的热交换,但是对路基阴、阳坡的影响存在差异.建议在严寒地区高速铁路路基阳、阴坡可以采取不同厚度的聚氨酯保温板,减小阴阳坡地温差异,保持季冻土路基温度变化稳定.     

Covariance breakdowns and connectedness of crude oil futures markets with non-synchronous data

ABSTRACT

This article identifies the breakdowns in the covariance of three benchmark crude oil futures markets (WTI, Brent and Dubai) and investigates the changes of market connectedness across the breakdown periods. As the crude oil futures are traded in different regions, this article eliminates the non-synchronous trading data by employing the Vector Moving Average structure and the Bayesian data augmentation approach, which keeps the integrity of original data without changing its properties. The results show that there are significant breaks in the covariance structure of crude oil futures markets. The breakdown periods are consistent with the periods when the market volatilities are at high level and the returns are volatile. The changes of market connectedness are independent of the covariance states, which supports the globalization hypothesis for the crude oil market. The results also suggest that there is more information flow out of the WTI than to the WTI during the sample period, particularly during the breakdown periods in 2008–2009.     

一种适用于强脉冲噪声下的对数型恒模盲均衡算法

针对脉冲噪声下恒模算法(Constant Modulus Algorithm,CMA)失败的问题，通过分析脉冲噪声的影响，提出了一种基于最小均方（Least Mean Square,LMS）准则的对数型恒模算法（Logarithmic-type CMA,LT-CMA）。LT-CMA利用对数函数的非线性变换特性自适应地抑制强脉冲噪声对误差函数的影响，并且利用l2-范数进行信号归一化处理以增强算法的稳健性。仿真结果表明，所提出的LT-CMA可以适应于高斯噪声环境和脉冲噪声环境；与经典自适应均衡算法相比，在收敛速度和稳健性两方面上，所提出的LT-CMA都有显著的提升。     

Forecasting value‐at‐risk in oil prices in the presence of volatility shifts

Recent evidence suggests shifts (structural breaks) in the volatility of returns causes non‐normality by significantly increasing kurtosis. In this paper, we endogenously detect significant shifts in the volatility of oil prices and incorporate this information to estimate Value‐at‐Risk (VaR) to accurately forecast large declines in oil prices. Our out‐of‐sample performance results indicate that the model, which incorporates both time varying volatility (without making any distributional assumptions) and shifts in volatility, produces more accurate VaR forecasts than several benchmark methods. We make a timely contribution as the recent more frequent occurrences of unexpected large oil price declines has gained significant attention because of its substantial impact on the financial markets and the global economy.     

Revisiting global economic activity and crude oil prices: A wavelet analysis

Based on the wavelet analysis approach, this paper firstly examines the dynamic relationship between global economic activity (proxied by the Kilian economic index) and crude oil prices in both time- and frequency-domains. Our empirical results demonstrate significant correlation between crude oil prices and global economic activity at high frequencies (in the short run) during the entire sample period; however, the co-movement between the two at low frequencies (in the long run) is weaker and exists only during certain proportions of the sample period. We also document evidence that global economic activity and oil price are positively correlated, with dynamic lead-lag relationships across time. Our findings are robust to alternative choices of oil price indexes and controlling for other confounding factors such as geopolitical risk, armed conflicts, economic policy uncertainty and equity market uncertainty. The current study provides valuable implications for oil market investors based on the information of global economic situation and its dynamic relationships with oil prices.     

Oil price and automobile stock return co-movement: A wavelet coherence analysis

This paper explores possible co-movement between oil price and automobile stock return in a joint time-frequency domain. Daily price series from August 01, 1996 to June 20, 2017 is used in this analysis. The results indicate that the co-movement between oil price and automobile stock return is strong during November, 2000–December, 2002 and March, 2006–December, 2009. The co-movement is found to be more pronounced in the long-term and stock return is sensitive to the higher oil price emanating from the demand shock. This contravenes the conventional wisdom that crude oil is always counter-cyclical to the automobile stocks. For investor, this weakens the probable gain from including oil asset in a portfolio of automobile stocks as crude oil does not offer cushion against bearish automobile stock markets during the crisis period.     

电改环境下油气管道企业用电成本管控研究

电力体制改革为油气管道企业用电成本管控提供了政策支持。在梳理电力改革政策的基础上,简要介绍了适用于油气管道企业的新电力政策,详细分析了我国油气管道企业存在的基本电费偏高、力调电费偏高、用电类型不合理、用电管理有待完善等用电现状及其根本原因。在上述分析的基础上,提出了选取合适的用电类别、选择合理的电费计费方式降低基本电费、提高功率因数降低力调电费、积极利用直购电政策、健全用电成本管控激励和考核机制等对策建议,以期为油气管道企业用电成本管控提供参考借鉴。     

油气企业供应商管理存在的问题与建议——以CS公司为例

伴随着供应链管理的应用与发展,越来越多的企业认识到必须充分利用内外资源保持自身的竞争实力。作为重要的外部资源,供应商管理关系到企业成本与收益的平衡,而要做好供应端的成本管理首先要做好供应商的选择和优化。针对CS公司的供应商管理现状及存在的问题,探索适应企业的可操作性强的对策,以期为我国大型油气企业的供应商管理实践提供一定的参考。     

基于均方差法的郑州市土地综合承载力评价

［目的］开展土地综合承载力评价是科学编制国土空间发展战略的基础。通过构建包含水土资源承载力、经济承载力和生态承载力3个维度土地综合承载力评价指标体系，定量刻画郑州市城市土地综合承载力的特征与轨迹。［方法］运用均方差法，选取2010—2016年郑州市城市土地综合承载力评价指标，分析其土地综合承载力特征。［结果］（1）总体上，郑州市城市土地综合承载力不断增强，水土资源承载力呈现先升—降—升的动态演变特征； 经济承载力持续增长，这源于郑州市土地经济效益的大幅提升； 生态承载力呈现波动性增强的演变特征。（2）郑州市城市土地综合承载力经历了较低—中等—较高发展历程，但土地综合承载力处于低层次的较高阶段，仍有较大提升空间。（3）为提高郑州市城市土地综合承载力，应加快“多规合一”规划的编制，科学划定城市增长边界和“三生”空间，转变城市发展理念，优化发展发展路径，提升城市土地综合承载力水平。［结论］郑州市城市土地综合承载力仍有较大提升空间，应加快建立土地综合承载力扩容的有效机制。