| 电感耦合等离子体原子发射光谱法测定聚乙烯、聚丙烯中铬、锆、钒和铪 |
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| 引用本文： | 陈金凤,陈章捷,钟坚海,郑宗展.电感耦合等离子体原子发射光谱法测定聚乙烯、聚丙烯中铬、锆、钒和铪[J].检验检疫科学,2011(4):39-41,62. |
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| 作者姓名： | 陈金凤 陈章捷 钟坚海 郑宗展 |
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| 作者单位： | 龙岩出入境检验检疫局; |
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| 摘 要： | 采用微波消解技术对以聚乙烯、聚丙烯为原料制作的食品容器、食品包装薄膜进行预处理,确定了溶样酸介质及其用量、微波消解温度、时间等关键因素,建立了一种快速测定聚乙烯、聚丙烯材料中铬、锆、钒和铪含量的电感耦合等离子体原子发射光谱法。实验结果表明,5mL硝酸和1mL过氧化氢的混合溶液即可实现样品的完全消解,同时通过优化光谱分析条件,得到铬、锆、钒和铪的检测限分别为1.0 mg/kg,0.7mg/kg,0.7 mg/kg,1.4 mg/kg。该法加标回收率在88%-103%之间,相对标准偏差（n=3）为0.84-6.4%。用于实际样品的测定,所得结果与标准样品的参考值相符。
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| 关 键 词： | 电感耦合等离子体原子发射光谱法 聚乙烯 聚丙烯 铬 锆 钒 铪 |
Determination of Chromium,Zirconium,Vanadium and Hafnium in Polyethylene and Polypropylene by Inductively Coupled Plasma Atomic Emission Spectrometry |
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| Chen Jinfeng,Chen Zhangjie,Zhong Jianhai,Zheng Zongzhan.Determination of Chromium,Zirconium,Vanadium and Hafnium in Polyethylene and Polypropylene by Inductively Coupled Plasma Atomic Emission Spectrometry[J].Inspection and Quarantine Science,2011(4):39-41,62. |
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| Authors: | Chen Jinfeng Chen Zhangjie Zhong Jianhai Zheng Zongzhan |
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| Institution: | Chen Jinfeng1,2,Chen Zhangjie1,Zhong Jianhai1,Zheng Zongzhan1,2(1.Longyan Entry-Exit Inspection and Quarantine Bureau,Longyan,Fujian,364000,2.State Key Testing Laboratory of Mineral) |
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| Abstract: | A method for the rapid determination of chromium,zirconium,vanadium and hafnium in polyethylene and polypropylene by inductively coupled plasma atomic emission spectrometry was established.The samples made of polyethylene and polypropylene used as food container or food wrapper was pretreated by microwave digestion.The effects of digestion media and it's use amount,digestion temperature and holding time on digestion results were investigated.It was experimentally indicated that the samples could be thorough... |
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| Keywords: | ICP-AES Polyethylene Polypropylene Chromium Zirconium Vanadium Hafnium |
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