| 二元溶液热力学性质的表达形式 |
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| 引用本文： | 李小平,韩其勇,宋波,王福明.二元溶液热力学性质的表达形式[J].河北工业科技,1994(4). |
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| 作者姓名： | 李小平 韩其勇 宋波 王福明 |
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| 作者单位： | 北京科技大学，北京科技大学，北京科技大学，北京科技大学 |
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| 摘 要： | 根据连续性原理,宏观热力学量是微观统计的结果和最小作用原理,导出关于混合自由焓△G~M 的微分方程,对于不同的本征值可解出理想溶液,正则溶液及亚规溶液等十分有意义的表达形式.
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| 关 键 词： | 溶液 混合自由焓 热力学性质 |
On the Formalism of Macroscopic Laws of Thermodynamic Properties of Binary Solution |
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| Li Xiaoping Han Qiyong Song Bo Wang Fuming.On the Formalism of Macroscopic Laws of Thermodynamic Properties of Binary Solution[J].Hebei Journal of Industrial Science & Technology,1994(4). |
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| Authors: | Li Xiaoping Han Qiyong Song Bo Wang Fuming |
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| Institution: | Beijing University of Science and Technology |
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| Abstract: | According to the principle of continuity and least action,and the fact that thermo- dynamic quantites are the statistical results of microstates,a differential equation for the macroscopic laws of binary solution is deduced.For the corresponding eigen value,the meaningful formalism of idea solution,regular solution,sub-regular solution and so on are obtained. |
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| Keywords: | solution mixing free enthalpy thermodynamic properties |
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