| 喷墨印刷／软光刻技术结合气相聚合法制备聚3，4-乙撑二氧噻吩图像 |
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| 引用本文： | Jong Seob Choi,Kuk Young Cho,Jin-Heong Yim,孟维华[编译].喷墨印刷／软光刻技术结合气相聚合法制备聚3，4-乙撑二氧噻吩图像[J].中国印刷物资商情,2010(4):99-100. |
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| 作者姓名： | Jong Seob Choi Kuk Young Cho Jin-Heong Yim 孟维华[编译] |
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| 作者单位： | [1]Division of Advanced Materials Engineering, Kongju National University, 182 Sinkwan-dong, Gongju City, Chungnam 314- 701, Republic of Korea [2]不详, Kongju National University, 182 Sinkwan-dong, Gongju City, Chungnam 314- 701, Republic of Korea |
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| 摘 要： | 采用气相聚合，以咪唑衍生物为辅助料可以成功制备高导电透明的聚3，4-乙撑二氧噻吩（PEDOT）薄膜。带有1～2个烷基官能团的咪唑衍生物的加入可以显著提高PEDOT的电导率。为了研制一种易于实现的PEDOT成像法，本文采用了喷墨印刷或软光刻技术结合气相聚合法，并以带取代基的对甲苯磺酸铁为氧化剂，3，4-乙撑二氧噻吩为聚合单体来制备PEDOT图像。这种新型方法的实现将为制得本征导电高分子材料图像提供一个高效便捷的方法。
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| 关 键 词： | 咪唑衍生物 喷墨印刷 聚3，4-乙撑二氧噻吩 软光刻技术 气相聚合 |
Micro-Patterning of Vapor-Phase Polymerized Poly （ 3,4-ethylenedioxythiophene） using Ink-Jet Printing/Soft Lithography |
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| Abstract: | Highly conductive and transparent poly（3,4-ethylenedioxythiophene） （PEDOT） thin films can be prepared effectively via vapor-phase polymerization （VPP） with the addition of imidazole （Im） based derivatives. The addition of Im that has one and/or two alkyl substituents significantly improved the electrical conductivity of PEDOT thin films. In an effort to develop a facile PEDOT micro-patterning method, we investigated ink-jet printing and soft lithography. The procedure of oxidant patterning with a weak base followed by VPP of a 3,4-ethylenedioxythiophene （EDOT） monomer provides an effec- tive and simple method for micro-patterning of an intrinsic conductive polymer （ICP）. |
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| Keywords: | Imidazole derivatives Ink-jet printing Poly （3 4-ethylenedioxithiophene） Soft lithography Vapor-phase poly- merization |
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