Can geotextiles modify the transfer of heavy metals transported by stormwater in infiltration basins?

Geotextiles are fibrous materials increasingly employed for the design of infiltration basins. However, their influence on the transfer of contaminants carried by stormwater has not been fully investigated. This study, based on column leaching experiments, aims at showing the effect of geotextiles on the transfer of three heavy metals (Zn, Pb and Cd) in a reactive soil (simulating an infiltration basin at laboratory scale). This effect depends on several factors, such as type of geotextile, hydric conditions (geotextile water content), hydraulic conditions (flow-rates) and the number of geotextiles installed. In all cases, geotextiles influence heavy metal retention by modifying flow and thus regulating contact between these metals and the reactive soil.     

Hydrological analysis of single and dual storage systems for stormwater harvesting

As stormwater flows are intermittent, the requirement to store urban runoff is important to the design of a stormwater re-use scheme. In many urban areas, the space available to provide storage is limited and thus the need to optimise the storage volume becomes critical. This paper will highlight the advantages and disadvantages of two different approaches of providing storage: 1) a single shallow storage (0.5 m depth) in which stormwater capture and a balanced release to supply users is provided by the one unit; and 2) a dual system in which the functions of stormwater capture and supply release are provided by two separate deeper storage units (2 m depth). The comparison between the two strategies is supported by water balance modelling assessing the supply reliability and storage volume requirements for both options. Above a critical volumetric capacity, the supply yield of a dual storage system is higher than that from a single storage of equal volume mainly because of a smaller assumed footprint. The single storage exhibited greater evaporation loss and is more susceptible to algae blooms due to long water residence times. Results of the comparison provide guidance to the design of more efficient storages associated with stormwater harvesting systems.     

Temporal evolution and spatial distribution of heavy metals in a stormwater infiltration basin--estimation of the mass of trapped pollutants.

Infiltration systems are widely used to manage stormwater in urban areas but questions about their long term sustainability need to be addressed. The possible pollution of the groundwater and the concentration of pollutant trapped in the soil are of major interest. This article focuses on the concentration of heavy metals found in the top layer of an infiltration basin. Two sampling campaigns have been undertaken 10 months apart and 200 samples were collected and analysed for lead (Pb), zinc (Zn) and copper (Cu). High concentrations were measured at the surface of the system; pollutant build up over time is clearly evident, especially in the lower lying areas, as well as higher concentrations in the oldest part of the system. Finally, the total mass of heavy metals trapped in the top layer of the systems are evaluated.     

Pollutant removal efficiency of alternative filtration media in stormwater treatment.

Sorption experiments were used to assess the ability of various materials (sand, compost, packing wood, ash, zeolite, recycled glass and Enviro-media) to remove heavy metal contaminants typically found in stormwater. Compost was found to have the best physicochemical properties for sorption of metal ions (Cu, Zn and Pb) compared with sand, packing wood, ash, zeolite and Enviro-media. The compost sorption of these metal ions conformed to the linear form of the Langmuir adsorption equation with the Langmuir constants (q,) for Zn(ll) being 11.2 mg/g at pH 5. However, compost was also found to leach a high concentration of dissolved organic carbon (DOC, 4.31 mg/g), compared with the other tested materials. Various combinations of sand, compost and other materials were observed to have excellent heavy metal removal (75-96% of Zn and 90-93% of Cu), with minimal DOC leaching (0.0013-2.43 mg/g). The sorption efficiency of the different Enviro-media mixes showed that a combination of traditional (sand) and alternative materials can be used as an effective medium for the treatment of dissolved metal contaminants commonly found in stormwater. The application of using recycled organic materials and other waste materials (such as recycled glass) also provides added value to the products life cycle.     

Removal of toxic heavy metals by iron-coated starfish.

In this study, the applicability of calcined starfish (SF) and iron-coated SF (ICSF) as potential adsorbents for the treatment of wastewater containing heavy metal ions was evaluated. ICSF was prepared by mixing FeCl(3) solution previously adjusted to pH 7 approximately 9 with SF at 105 degrees C. From the dissolution test at pH 2, ICSF showed strong acid-proof properties. In the batch adsorption, Cu(II) adsorption onto ICSF was completed within 150 minutes, while 47% Cu(II) was removed with SF alone. This result clearly suggests that the coated Fe(III) serves additional adsorption sites, resulting in the enhanced removal of heavy metal ions. The removed fraction of both Cu(II) and Pb(II) increased with increasing solution pH and nearly complete removals of Pb(II) and Cu(II) were observed at around pH 6 and 8, respectively. From the adsorption isotherm of Cu(II) onto SF and ICSF at pH 3.0, the removed amount of Cu(II) by ICSF was greater than that by SF over the entire concentration range studied. In the column test, the breakthrough of Cu(II) in the ICSF column was greatly retarded compared to that in the SF column. Based on the drinking water regulations for Cu(II), SF and ICSF were able to remove 3400 and 8600 mg/kg of Cu(II) from the wastewater, respectively.     

重金属在水体中迁移转化过程分析

通过分析各因素对重金属吸附影响的特点,介绍了重金属吸附过程的三种模式,由此得出水、体中重金属的释放主要由盐度变化、氧化还原反应条件的变化、pH值的变化、天然或人工合成的强络合剂的使用等化学变化引起的结论。此外,微生物的活动也会引起重金属的释放,同时,对重金属在水体中释放过程研究方法进行了探讨。     

Retention of 2,4,6-trinitrotoluene and heavy metals from industrial waste water by using the low cost adsorbent pine bark in a batch experiment

Pine bark is a low cost sorbent originating from the forest industry. In recent years, it has been found to show promise as an adsorbent for metals and organic substances in contaminated water, especially landfill leachates and storm water. This study aims to investigate if pine bark can replace commercial adsorbents such as active carbon. An industrial effluent, collected from a treatment plant of a demilitarization factory, was diluted to form concentration ranges of contaminants and shaken with pine bark for 24 hours. Metals (e.g. Pb, Zn, Cd, As and Ni) and explosives, e.g., 2,4,6-trinitrotoluene (TNT), were analysed before and after treatment. The aim of the experiment was twofold; firstly, it was to investigate whether metals are efficiently removed in the presence of explosives and secondly, if adsorption of explosive substances to pine bark was possible. Langmuir and Freundlich isotherms were used to describe the adsorption process where this was possible. It was found that metal uptake was possible in the presence of TNT and other explosive contaminants. The uptake of TNT was satisfactory with up to 80% of the TNT adsorbed by pine bark.     

Comparative uncertainty analysis of copper loads in stormwater systems using GLUE and grey-box modeling.

In this paper two attempts to assess the uncertainty involved with model predictions of copper loads from stormwater systems are made. In the first attempt, the GLUE methodology is applied to derive model parameter sets that result in model outputs encompassing a significant number of the measurements. In the second attempt the conceptual model is reformulated to a grey-box model followed by parameter estimation. Given data from an extensive measurement campaign, the two methods suggest that the output of the stormwater pollution model is associated with significant uncertainty. With the proposed model and input data, the GLUE analysis show that the total sampled copper mass can be predicted within a range of +/-50% of the median value (385 g), whereas the grey-box analysis showed a prediction uncertainty of less than +/-30%. Future work will clarify the pros and cons of the two methods and furthermore explore to what extent the estimation can be improved by modifying the underlying accumulation-washout model.     

Influence of compost characteristics on heavy metal sorption from synthetic stormwater.

This paper has the aim to assess the ability of garden derived compost to remove dissolved heavy metal contaminants typically found in stormwater. Compost was found to have excellent chemical and physical properties for the sorption of dissolved metal ions (Cu2+, Pb2+ and Zn2+). Batch sorption data were used to determine the sorption efficiency of Cu (93%), Zn (88%) and Pb (97%) by compost. The relative sorption affinity of these metals by compost is found to be in the order of Pb2+ > Cu2+ Zn2+. The effect of different particle size fractions of compost upon the sorption of Cu was also investigated. Sorption conformed to the linear form of the Freundlich isotherm and can be considered favourable because the sorption intensity values obtained in this study are between 0.1 and 1. Compost with a smaller particle size fraction has larger surface areas and greater sorption than the larger particle size fraction. Compost derived from garden waste is efficient for removal of heavy metals from wastewater or treating water for industries.     

利用沸石去除电镀废水中重金属离子的试验研究

天然沸石经过适当改性后用于去除电镀废水中重金属离子的试验结果表明:沸石具有较好的离子交换性能,可同时去除电镀废水中的Zn,Cr,Ni等重金属离子,以确保电镀废水达标排放。采用沸石进行电镀废水处理时,其最佳过流速度为4～5m/h,此时,Zn,Cr,Ni的有效去除率分别达到80%,60%,40%以上,工作周期可长达12h以上。     

实时控制系统提升调蓄池处理能力的模拟研究

为了评估智能实时控制系统对初雨调蓄池工程运行效率的提升效果,指导相关工程设计,构建了由SWMM与SUSTAIN组成的模型系统,并使用天津市2001至2010年间历史降雨数据模拟分析了使用智能实时控制系统前后,雨水调蓄池的运行状态和削减雨水径流污染的情况.通过分析降雨过程中调蓄池体的运行状态,得出智能实时控制系统通过"及...     

重金属废水生物处理技术

主要从生物法去除废水中重金属的原理,重金属废水生物处理技术,及重金属废水生物处理的影响因素等方面,综述了国内外有关重金属废水生物处理技术的研究成果,并介绍了重金属废水生物处理的工程应用,提出关于重金属废水生物处理的研究方向。     

长寿湖水库沉积物中重金属来源及生态风险评价

水库作为生活饮用水水源地,受人类活动影响较大,且污染物种类多、来源广、危害大。目前,关于水库沉积物中重金属污染状况分析的研究较少。以三峡库区长寿湖水库沉积物为研究对象,利用地累积指数(I_(geo))和潜在生态风险指数法,结合沉积年代学序列,对沉积物中重金属Co,Cd,Cr,Cu,Ni,Pb和Zn的垂直变化特征、重金属来源及生态风险评价进行了分析。地累积指数分析表明:表层沉积物中重金属累积顺序为CdCoZnNiPbCuCr,其中Cd和Zn累积较明显,属于轻度污染。潜在生态风险系数评价结果表明:沉积物中重金属潜在生态风险指数RI值大多数低于150,说明潜在生态风险整体较轻,但自1889年以来,RI值一直大于150,应当引起重视。应用主成分析法分析长寿湖水库沉积物中重金属来源,结果表明:水库沉积物中重金属主要来源于流域土壤的自然风化和土壤侵蚀,同时也受到龙溪河流域城市化、工业化发展导致的工业废水和生活污水排放的影响。     

Coupled reduction of chlorinated hydrocarbons and heavy metals by zerovalent silicon.

The feasibility of using zerovalent silicon (Si0) as a novel reductant to remove chlorinated compounds and heavy metals in contaminated sites was investigated. The kinetics and degradation mechanism of carbon tetrachloride (CT) by Si0 were also examined. Results showed that zerovalent silicon could effectively dechlorinate the chlorinated compounds. A nearly complete dechlorination of CT by Si0 was obtained within 14 h. The produced concentrations of chloroform (CF) accounted for 71-88% loss of CT, showing that reductive dechlorination is the major degradation pathway for the degradation of chlorinated hydrocarbons by Si0. The degradation followed pseudo first-order kinetics and the normalized surface reaction rate constant (k(sa)) for CT dechlorination ranged between 0.0342 and 0.0454 L m(-2) h(-1) when CT concentrations were in the range of 3-20 microM. A linear relationship between the k(sa) and pH value was also established. In addition, zerovalent silicon has a high capability in the removal of heavy metals. 83% of Cr(VI) was removed by 0.5g Si0 within 5 h, which is higher than that by Fe0. The removal efficiency of divalent metal ions by Si0 followed the order of Cu(II) > Pb(II) > Ni(II). This indicates that zerovalent silicon is an alternative reductant and can undergo coupled reduction of heavy metals and chlorinated hydrocarbons in contaminated groundwater.     

Accumulation of heavy metals in the physical and biological systems of Lake Koka,Ethiopia: Implications for potential health risks

Lake Koka has several important socioeconomic uses, hydroelectric power generation, domestic water supply, irrigation, recreation and fishery. It is currently under serious threat, however, because of point and nonpoint pollution inputs. The objective of the present study was to examine the concentration of heavy metals (Mn, Cr, Pb, Zn, Cu, Ni and Cd) and their bioaccumulation, and biomagnification factors along the lake's food chain in order to assess the potential human and ecological health risks. Water, sediment and plankton samples were collected from seven sampling sites and fishes were purchased on site from fishers. The analyses were performed using a graphite furnance atomic absorption spectrophotometer. Heavy metals levels in the sediment samples were ranked in the order of Mn > Cr > Pb > Zn > Cu > Ni > Cd. Similarly, the metal concentration in the fish muscles was Cr > Cu > Pb > Cd. The sediment bioaccumulation factor (<1) and water bioaccumulation factor (>1) for Cd, Pb and Cr indicated the lake water exhibited higher concentrations than the sediment. In parallel, the Cr biomagnification factor for zooplankton, catfish, Nile tilapia and common carp was 1.63, 1.18, 1.36 and 2.28, respectively. The Cr concentrations at the Modjo (or Mojo) Upstream, Modjo Downstream and Kentare sites, and the Pb concentrations at riverine sites were above the permissible limits established by the World Health Organization. Cr ranked as fish species > zooplankton > phytoplankton, being above the permissible limits in catfish, Nile tilapia and common carp. Generally, the weekly intake estimates were considerably lower than the tolerable human intake values provided by WHO and others. However, Cr biomagnified along the trophic levels ultimately reaching the top consumers, with Cr (VI) being carcinogenic. The lake is a major fishery source, indicating care must be taken in regard to the weekly intake of the fishes, particularly common carp.     

Statistical analysis of pollution in stormwater infiltration basins.

In order to characterize soil pollution in stormwater infiltration basins, four basins of the Lyon area were selected and sampled. Altogether, 66 soil samples were collected. Each sample was analyzed for pH, cationic exchange capacity, particle size distribution, total organic carbon, total nitrogen, total phosphorus, metals, total hydrocarbons and polycyclic aromatic hydrocarbons (PAHs). Data was explored in a classic way (soil profiles) and using multivariate analysis techniques. Two methods were applied: Principal Component Analysis (PCA) and Cluster Analysis (CA). Main results are presented in this paper. Pollutant concentrations decrease rapidly with depth while pH and grain size increase. Sustainable concentrations are reached at a 50-cm depth, even after 21 years of operation. Multivariate analysis shows how pollution affects each sampling depth.     

Biosorption of heavy metals onto nonliving Laminaria japonica

In this paper, study of the biosorption of Cd(2+) and Pb(2+) by nonliving Laminaria japonica in a batch adsorption system is described. The content of acidic sites and the dissociation constant of carboxylic acid functional groups (metal-binding site) of L. japonica were experimentally determined by conductometric and potentiometric titrations and theoretically predicated by using monodentate and bidentate binding models. The models are based on the monodentate or bidentate binding reactions of bivalent metal ions to acidic sites. The acidic site content and carboxylic acid dissociation constants determined are 1.25 and 0.18 mmol L(-1), respectively. The results showed that the bidentate adsorption model fits well the biosorption of bivalent metal ions onto L. japonica with the bidentate binding constants for Cd(2+) and Pb(2+) being 5.72 × 10(3) and 6.24 × 10(4) L mol(-1), respectively. The adsorption process of L. japonica followed the pseudo-second-order kinetics.     

Behaviour of heavy metals during tertiary bio-filtration.

More stringent water quality parameters in the Annex of the Water Framework Directive 2000/60/EC led to the introduction of "Maximum Tolerable Risk concentrations" (MTR-values) in the national legislation in The Netherlands (Vierde Nota Waterhuishouding). The MTR-values give limitations for the concentrations of e.g. heavy metals (HM's) but also for nutrients: Ntot < 2.2 mg/l, Ptot <0.15 mg/l. Investigations of HM removal during denitrifying flocculation filtration are conducted on the effluent of a typical modern Dutch WWTP. Because of low concentrations of HM's in the feed water, a cocktail of copper, nickel and zinc chloride (approximately equal 150-200 microg/l) is dosed before filtration. Preliminary jar tests and filtration tests with media filtration in pilot-scale and lab-scale are conducted. The results show high removal of nickel and zinc during jar tests with dosing of powdered activated carbon. During filtration tests at pilot-scale the bounded fraction of copper and zinc is highly removed. All three HM's are removed in the lab-scale activated carbon filter. After dosing, nickel is found mainly in the dissolved form, but it is removed in the lab-scale activated carbon filter. The removal of HM's via adsorption subsequently leads to a discussion on the toxicity of HM's and their bio-availability.     

Performance comparison between infiltration and non-infiltration type of structural stormwater treatment systems

The study was constructed to monitor representative inflow and outflow from infiltration and non-infiltration type best management practice (BMP) sites developed at a university campus, allowing the determination of overall performance efficiency in terms of runoff reduction and pollutant removal. Based on the monitored storm events, the runoff and discharged volume and flow rates exhibited high positive correlations with total rainfall depth (p<0.001). Findings revealed that as the total rainfall increases, the amount of volume reduction and pollutant removal decreases for both types of BMP. Infiltration BMP showed a higher ability in treatment performance especially during small storm events than non-infiltration type; however, the differences were not significant. Pollutant removal rates of infiltration type were in the range of 70-90% while between 35 and 80% for the non-infiltration type for storm events with less than 10 mm rainfall depth. Average volume reductions were 71 ± 33% and 32 ± 32% for the infiltration and non-infiltration type, respectively. The ratio of the discharge volume was significantly greater than the ratio of discharge pollutant load indicating a high potential for water quality improvement. Design recommendations were provided considering sizing and cost for on-site application of similar BMP designs in the future.     

苏州河沿岸排水系统雨水调蓄池设计方案探讨

探讨了通过式雨水调蓄池长期平均运行效率的评价方法,对影响调蓄池类型选择与运行效率的主要因素--雨天出流的初期效应及悬浮物沉降性能进行了分析.针对上海市苏州河沿岸排水系统雨天出流的特性,提出了调蓄池形式优化选择的策略:对于存在一定初期效应且沉降性能差的合流制系统采用存储池;而对于基本无初期效应、出流中污染物沉降性能好的分流制系统采用存储-沉淀池.