催化柴油加氢精制催化剂的研究

研制出以物质A和氧化铝为复合载体,以钨-镍为活性组分的柴油加氢精制催化剂;以大庆重油催化轻柴油为原料,在反应压力7.0 MPa,氢油体积比500:1,体积空速0.8h-1,反应温度330℃的工艺条件下,生成油硫含量＜15μg/g,满足世界燃油规范Ⅲ类清洁柴油标准.     

柴油加氢精制催化剂的设计

随着国内外清洁柴油标准的不断提高及需求量的日益增长,柴油加氢精制技术作为改善柴油质量的最有效手段得到广泛的应用和发展,高性能柴油加氢精制催化剂的研发成为深入研究的重要课题.本文通过深入剖析柴油加氢反应机理提出催化剂的设计思路,同时针对加氢反应的难点问题进行深入分析,并根据上述分析结果开展柴油加氢催化剂的研制工作.     

柴油馏分油加氢精制催化剂载体的探讨

本文介绍了柴油加氢精制催化剂载体的选择、扩孔及改性。利用研制的载体制备出了柴油加氢催化剂,并在100mL小型加氢装置上进行了活性评价,研制剂活性优于国内参比剂。并在大庆石化公司炼油厂两套柴油加氢装置实现首次工业应用成功。     

DZD-1柴油加氢精制催化剂的性能及工业应用

研制出以改性的国产γ-Al2O3为载体,以钨镍为活性组分的DZD-1柴油加氢精制催化剂,并通过了活性稳定性试验。以大庆石化公司炼油厂催化柴油和焦化柴油的混合油为原料,在氢分压8.0MPa、体积空速2.5h-1～2.7h-1、氢油比340:1～360:1、反应器床层平均温度327～380℃的工艺条件下,可生产出硫含量小于50μg·g-1的柴油。     

新型高效劣质柴油深度脱硫脱芳催化剂的研制

以溶胶-凝胶合成法结合CO2超临界干燥技术制备了性能优良的介孔TiO2-SiO2复合氧化物.以复合氧化物为载体,金属Ni-W或Pt/Pt-Pd为加氢组分,采用浸渍法制备的催化剂,采用两段加氢工艺,以大庆重催柴油为原料,在100 mL加氢装置上的评价结果表明,以TiO2-SiO2复合氧化物为载体制备的加氢催化剂,具有良好的加氢脱硫、脱芳性能,能使柴油的硫和芳烃指标达到<世界燃料标准>Ⅲ类柴油指标要求.     

国内清洁柴油的加氢技术进展

由于环保法规的出台和原油劣质化的日益严重,深度加氢脱硫技术及相应的催化剂研究成为热点。分析了中国清洁柴油生产对加氢技术的需求,介绍了国内两家主要加氢研究机构中国石化抚顺石油化工研究院和中国石化石油化工科学研究院的清洁柴油加氢技术。这些技术均已成功地应用于工业生产,为企业生产高质量清洁柴油提供适时有力的技术支撑,增加了企业的经济和社会效益。此外还对中国生产清洁柴油的方向提出了建议。     

生产低硫柴油技术的新进展

本文综述了国内外低硫柴油生产技术，主要从加氢脱硫和非加氢脱硫两个方向介绍了低硫柴油技术的原理、特性及研究进展，并分析了今后低硫柴油生产技术的发展方向。     

劣质柴油加氢精制/异构降凝催化剂的研制及工艺开发

研制了柴油加氢精制/异构降凝催化剂,分别采用大庆石化公司炼油厂焦化柴油及混合油[w(焦化柴油)∶w(催化柴油)=55∶45]为原料,在小型串联加氢评价装置(200 mL)上进行了加氢精制和加氢降凝两种方案的评价。试验结果表明:通过调整工艺参数,可使装置分别按精制和降凝两种方案运行,并且使柴油的各项性质指标均有了大幅度的提高。     

重整预加氢精制催化剂的开发及工业应用

研制出以改性氧化铝为载体，以钴、钼、镍为活性金属组分的重整预加氢催化剂DZ-1A，并且通过了小试、中试、活性稳定性试验。以大庆石化公司炼油厂常顶汽油为原料，在反应压力1．25MPa、体积空速2．5h^-1、氢油体积比120：1、反应器平均温度271℃的工艺条件下，利用DZ-1A催化剂可生产出符合重整催化剂要求的汽油原料。     

甲基叔丁基醚作助溶剂合成生物柴油研究

以地沟油为原料,测定了地沟油中水分和酸价,研究了助溶剂对催化地沟油制备生物柴油的影响,考察了助溶剂的用量、催化剂用量、反应温度、反应时间、对制备生物柴油的影响。结果表明:地沟油水分含量为3.75%,酸价为172mgKOH/g,甲基叔丁基醚作助溶剂可以显著提高生物柴油的转化率,地沟油油制备生物柴油最佳工艺条件是:反应温度75℃,催化剂用量为油量的5%,甲基叔丁基醚用量为油量的25%,反应时间为8h,在此条件下生物柴油的得率为95.91%。     

Brown＇s Blossom in Britain-China

The overall strategic relationship between U.K. and China is ＂better than ever＂, China- Britain relations have maintained good momentum, with increased high-level exchanges and the reinforcement of strategic mutual trust, with more room for growth in the future.     

Challenge and Opportunity Go Hand in Hand——What Global Economic Agitation Brings to the China's Economy?

Domino effects of the global finance agitation As the origin of the subprime crisis,US financial institutions lost USS45 billion last year,accounted for over half of the total US,EU & Japan loss.Since January 15th,Chtigroup released its financial statement of the 4th quarter,showing a net deficit of USS9.83 billion,which marked the hisoric high of its quarterly deficit.     

Jean-Pierre Duprieu： Willing to Be A Legate of Sino-French Business

Estaing, former French president, Valery Giscard d＇Estaing attended Sino-French Economic Seminar held in Shanghai in early April and said that the world center has shifted from the west to the east with many European and US companies entering into Asia, and China has the ability to play an important role in the world stage. Estaing, naming himself＂French Confucian＂, then said in Chinese that a cook-group includes 10 people in ancient Chinese soldier system and the cook is in charge of cooking for them. And people who belong to the same cook are actually ＂Partners＂.     

China''''s Stock Market Wave

The annual meeting of the World Economy Forum was held in Davos,a little town in Switzerland,on January 23rd to the 27th this year,with the theme"the Power fo Collaborative Innovation",over 2500 celebrates from ture political and cconomic circles of more than 80 countries and challengred logether to talk about the future of the global economy in 2008,A Forum for the problems and challenges that face whole world,some of the keywords which drew attention during the event were:the U.S.subprime mortgage crisis,soaring energy prices,the economic slowdown in the U.S.ermerging economic bodies,authority funds and the general unpredictable nature of the global economy.     

Trade Promotion from Neighborhood

If you are considering to trade with companies in Japan or expanding your .business to Japan, we are ready to help from the very beginning.＂ You will find this greeting at the first sight on the Chinese website of Japan External Trade Organization （JETRO）. JETRO has committed itself in delivering highly efficient and quality services to meet the demand of internal and external customs including Japanese companies, hence winning a good reputation in the international trade arena. In recent years, with its priority in advancing business cooperation in South and East Asia, JETRO has made great achievement in promoting trade between China and Japan. Therefore, China＇s Foreign Trade interviewed Mr. Yoichi Maine, Deputy Director General of JETRO BEIJING.     

Auto Parts Market Potential Coming into Surface

Looking at the increasingly fierce competition in the world auto market. global automobile manufacturing industry, taking Europe, the U.S. and Japan as representatives, is gradually forming a new type of relationship, mutual cooperation between whole vehicle and parts manufacturers. We can clearly see that auto parts manufacturers have become independent from the whole vehicle manufacturing companies, which means that the former structure of auto industry has greatly changed, and a new relationship,     

Domino Effect on Electricity and Coal Prices

In the middle of last December, the key purchase contracts for coal used in power generation in 2008 were signed, reflecting a demand for more than 1.085 billion tons. It is important to note that the country＇s five biggest power producers, China Huaneng Group, China Guodian Corporation, China Power Investment Corporation, China Huadian Corporation and China Datang Corporation, had settled on the prices on their purchase contracts, and they are expected to consume 290 million tons of coal for generating electricity,     

Slimmed May Day Holiday

Last November the State Council of China decided to renew its holiday system by reducing the seven-day May Day holiday to three days and introducing three new one-day public holidays, namely the Qingming Festival, Dragon Boat Festival and Moon Festival. By doing so, the three golden-week holidays that were introduced in 1999, namely the Spring Festival, May Day and National Day, could be better distributed.     

China Ranked the 7th in Global Influence Survey

The results of the Annual Global Public Opinion Survey were released by the British Broadcasting Company （BBC） on April 2,2008,the combination of 7,457 public opinion polls in 34 countries,gave Germany and Japan the No.1 and No.2 spots,respectively, while the last four went to North Korea, Pakistan,Israel,Iran.     

Figures from Government Working Report

Nine o＇clock in the morning of March 5th,2008,the first meeting of the eleventh session of National People＇s Congress was held in the Great Hall of People.As usual,the first performance of this big event in China was from the government working report made by the Premier.Five years of government＇s work in this session was counted in Premier Wen Jiabao＇s working report.