THE EFFECT OF DETERGENT TYPE AND LAUNDERING TEMPERATURE ON THE SOIL REMOVAL AND SOIL REDEPOSITION PERFORMANCE OF COTTON AND P/C BLENDS WITH AND WITHOUT DURABLE PRESS FINISH

Three soiled test cloths of cotton and 65/35% Dacron/cotton blends with and without durable press finish were subjected to twenty-five repeated launderings in Launder-Ometer to determine the effect of fabric type, wash temperature, and laundering interval on the soil removal and soil redeposition performance. The reflectance of the test fabrics as measured by a Hunter Lab D-40 reflectometer and the amount of soil removed and redeposited was computed in reflectance unit (RU) expressing the difference in reflectance of the test samples before and after washing. Soil removal and redeposition performances were significantly influenced by fabric type, detergent type, and laundering interval. Duncan's multiple range test indicated that Dacron/cotton blends with and without durable press finish retained and redeposited significantly less soil than cotton. Powder detergents cleaned test fabrics better than liquid detergents. Highly significant correlations between soil removal and redeposition RU and whiteness measurements were found. Therefore, both computations serve as reliable methods to evaluate soil removal and redeposition performance.     

A survey of commercial laundry detergents - how effective are they?: Part III: powders,liquids and hard water

The effectiveness of 42 detergents, 11 non-phosphate containing powdered detergents, 12 phosphate containing powdered detergents, 11 unbuilt liquid detergents and eight built liquid detergents, of varying formulations, in cleaning a standard soiled fabric in water of varying hardness was evaluated. Powdered detergents were found to be significantly affected only at very high water hardness levels. There was no significant difference between washing in warm and hot water for the liquid detergents, except for a melaleucaoil based detergent which performed significantly better in hot water. Increasing water hardness had no significant effect on liquid detergents. Powdered detergents performed better than liquid detergents in cleaning the standard soiled fabric. While no one detergent was significantly better than the others, in general, washing with detergents that contained phosphates did give somewhat better results in warm water. Detergents that contained bleach as an additive did not result in whiter fabric.     

A survey of commercial laundry detergents – how effective are they? Part I: powders

The effectiveness of 11 non-phosphate containing powdered detergents and 12 phosphate containing powdered detergents, of varying formulations, in cleaning a standard soiled fabric in soft water (5 ppm) were evaluated. It was found that in soft water there were no differences between washing with either phosphate or non-phosphate detergent. In general, washing with detergents which contained phosphates did give somewhat better results in warm water. Detergents that contained bleach as an additive did not result in a whiter fabric.     

The effect of phosphate detergent bans on consumer clothing expenditures

Metropolitan sales data from the 1977 Census of Retail Trade were analysed to test whether phosphate detergent bans increased consumer expenditure on clothing: positive effects were found for men's clothing and domestic fabrics (sheets and towels). In areas with medium water hardness the average annual cost in 1977 equalled $11·08 per household. For 1984, the equivalent cost was $14·17 per household. These results are consistent with laboratory studies that show decreased detergency associated with non-phosphate detergents and increased fabric wear associated with carbonate-built detergents, the principle substitute for phosphate detergents. The bans impose the largest cost on hard water areas. In both ban and non-ban areas in 1977 higher laundering costs were associated with higher water hardness. Analysis of 1972 data indicated that water hardness did not affect clothing expenditures significantly when detergents contained large amounts of phosphates.     

A survey of commercial laundry detergents — how effective are they? Part II: liquids

The effectiveness of 11 unbuilt liquid detergents and eight built liquid detergents, of varying formulations, in cleaning a standard soiled fabric in soft water (5 ppm) were evaluated. It was found that in soft water there were no significant differences between washing in warm or hot water with either type of detergent, except for a melaleuca oil based detergent which was significantly better in hot water. However, although not significant, in general, washing with unbuilt liquid detergents did give somewhat better results in both warm and hot water.     

Bacterial survival on fabrics laundered in cold water

The effect of detergent formulation and fabric type on bacterial survival after home laundering in cold water was investigated. Three fabrics, 65/35 polyester/cotton shirting, 100% cotton sheeting, and 100% cotton terry cloth, were inoculated with Staphylococcus aureus, laundered in cold 60 ± 5°F (16 ± 3°C) water and machine dried. Eight phosphorus-based powders and non-phosphorus detergents in both powder and liquid form were used. A control with no detergent was used. Percent reduction in bacteria after machine washing and after machine drying were determined. Of the eight detergents studied, only two effectively removed 100% of the bacteria from the cotton terry cloth after washing. These were sodium carbonate and aluminosilicate-based powders, one of which contained sodium perborate, the other included enzymes. All of the detergents used removed > 97% of bacteria from the polyester/cotton shirting and cotton sheeting fabrics. No significant cross contamination occurred with any fabric. A greater percent reduction of bacteria was obtained with the terry cloth samples after washing and tumble drying than after washing alone. The implications of the study are important for consumers who are using colder water in the laundering process. This study found that bacteria were removed more easily from the two plain weave fabrics than the looped terry cloth fabric. The effectiveness of tumble drying after cold water laundering to reduce bacteria in the terry cloth towelling was an important finding.     

Detergent residues in textiles

The purpose of this study was to determine concentrations of detergent residues in textiles washed with three types of detergents. One detergent contained phosphate. In the other two (concentrated or ecological detergents) phosphate had been replaced by zeolite, which contains silicates. The textiles were washed using two programmes for coloured materials (at 60°C). The programmes differed with regard to volume of rinse water and number of rinsings. Detergent residues in textiles were determined chemically. Zeolite particles were determined electron microscopically. The results showed that most of the detergent residues remaining in textile strips were anionic tensides. They increased in proportion to the quantity of detergent used for washing. The least residues were left by concentrated detergents. Anionic tensides are suspected of causing skin irritation, probably allergy in atopic persons. Zeolite particles may irritate skin mechanically or cause through irritation respiratory distress. Washing programmes using less rinse water than other programmes increased detergent residues by 30%. It is concluded that there is a positive linear relationship between concentration of detergent and residues in textiles, and a negative linear relationship between water volume and residues in textiles after laundering. This could be of considerable importance from a health point of view and should be evaluated before any detergent is marketed. A methodology combining different standardized methods for analysing detergent residues in textiles was developed in this study.     

Detergents,clothing and the consumer with sensitive skin

A typical detergent formulation for domestic garment washing is a complex formulation comprising: surfactants, builders, bleaches and auxiliary agents. Repeated exposure to surfactants can cause damage to the lipid film layer of the skin. Textile constructions used in clothing are also complex. Most apparel fabrics will be subject to a laundering process containing detergent at some time in the life cycle and thus it can be surmised that the combination of clothing and detergent is likely to be the cause of some skin problems. Certain fibre types show higher absorption rates than others. If surfactants present in domestic detergents are preferentially absorbed into the fabric during laundering and inadequately removed by rinsing a build‐up of the surfactant may exacerbate skin irritation. This paper offers a review of the debate on the effects of detergents on skin disorders plus recent research on clothing and detergents.     

An investigation into some aspects of the efficiency of low-temperature laundering

The purpose of this research was to investigate the efficiency of laundering at low and recommended water temperatures using a heavy-duty biological detergent and a low-temperature detergent. The effectiveness of the process was measured in terms of the degree of stain/soil removal from laundered garments, and in the removal and transfer of bacteria from infected test pieces. The results indicate that with both detergents a reduction in washing efficiency occurs as the temperature of laundering is decreased, except when the difference between the recommended and low water temperature is small. Evidence was also obtained that shows that reducing wash temperatures decreases the degree of disinfection and increases the cross-infection of articles washed in the same load.     

Comparison of the washing efficiencies of a laboratory washing device (Launder‐Ometer) and of automatic household washing machines with horizontal drums

The objective of this study was to compare the cleaning result of a laboratory washing machine – Launder‐Ometer (LOM) – with that of drum‐type household washing machines, using detergent without bleaching agent, standard soiled fabrics and a colorimeter for assessing the washing result. The mechanical effect applied to the laundry in the household washers was not obtained in the LOM by increasing mechanical impact or the number of metal balls. Extended washing time did not improve removal of blood soil in the LOM, although it did increase removal of mayonnaise soil containing chlorophyll. However, in practice a washing time of 60–85 min is relatively long for a laboratory device considering the claimed time‐saving nature of these devices. None of the examined parameters affected removal of a red wine soil containing tannins, which was poor in all test combinations both in the household machines and in the laboratory washing machine. Bleaching agent is recommended for removal of this type of soil. In conclusion, conformity between washing results of the laboratory washing machine and the drum‐type household washing machines depends on the type of soiled test fabrics and other parameters in the washing process. Removal of blood soil differed most between the household machines and the LOM.     

THE COST OF WASHING CLOTHES: SOURCES OF VARIATION

This paper develops the national average cost of washing clothes by examining consumer research data on the frequencies of using various water temperature settings and laundry additives and by utilizing national surveys of laundry product prices. Variations in these costs are shown to be significantly affected by three variables: (1) costs increase with family size due to the higher number of loads washed, (2) costs increase in areas where phosphate detergents are not available due to an increased use of hot water and laundry additives and (3) costs increase in harder water areas due to an increased use of hot water and fabric softener. The average increased cost for energy and laundry additives per family due to the nonavailability of phosphate detergents exceeds $11.00 per year. In addition to this amount, increased wear on washing machine parts and fabrics from the use of carbonate-built detergents significantly increases the costs to consumers in nonphosphate areas.     

The effects of water hardness level on washing quality using commercial laundry detergents

The water hardnesses were determined for 10 samples of water. A wide variation of water hardnesses were found ranging from very soft to very hard. The effectiveness of six commercial laundry detergents of different formulations were evaluated. The detergent containing a non-ionic surfactant with a phosphate builder was found to give the best whiteness results, regardless of water hardness. Because of the possible environmental problems associated with the use of phosphates, consumers may wish to select the next most effective detergent formulation, which varied between water samples.     

Relationship of wash/rinse water temperatures to soil removal

Samples of cotton, polyester and nylon fabrics were soiled by application of synthetic sebum and clay and then laundered at various combinations of hot, warm and cold wash and rinse water temperatures. The temperature of the rinse water did not affect the amount of soil removed from the fabrics. More soil was generally removed with hot wash water than with warm or cold water. The soil was more readily removed from the nylon than from the cotton or polyester fabrics. All wash/rinse treatments removed soil to a level that would probably be acceptable to most consumers.     

HOME LAUNDERING PART II. A LABORATORY EVALUATION OF THE WASHING PERFORMANCE OF FOUR DETERGENT PRODUCTS AT 40°C

A detailed comparison of the washing performance of four detergent products is discussed. The results of experiments using stained tea and terry towels and fabrics having standard stains, clearly indicate that the performance of liquid home laundering formulations commercially available in the U.K. and France does not compare favourably with the results obtained from perborate-containing powder products.     

The effects of skirt lining properties on comfort and movement

This study was conducted to clarify the influences of the lining properties of skirts upon comfort and movement. The comfort of lining fabrics and real skirts with and without lining was rated by sensory tests on the basis of sensorial comfort on the skin and body movement. Actual body movements were investigated by motion analysis while the skirts were being worn. The results are described: (1) Comfort on the skin, movement and overall preference for the lining fabrics were evaluated by sensory testing, comparing skirts made with five kinds of lining fabrics. Conventional non‐stretch cupro lining was ranked first on the basis of smoothness and good feel to the skin. Two‐way stretch lining was also ranked highly in terms of ease of movement. We discuss how sensorial comfort on the skin and ease of movement related to overall preference for lining fabrics. (2) Sensory test of the actual skirts with and without lining clearly confirmed that lining played a role in improving comfort. (3) For a non‐stretch fabric skirt, conventional lining was ranked highly for good feel to the skin, and two‐way stretch lining was considered useful for ease of movement. There was no significant difference between the two lining fabrics in overall preference. (4) For a stretch fabric skirt, stretch lining is the most useful because it maintains easy extension of the outer fabric, thus allowing ease of body movement. (5) Motion analysis showed that a combination of knitted stretch skirts with stretch lining was the best for ease of movement. Comparing the sidelines and the hemline of the stretch fabric skirts demonstrated a better shape using lining.     

洗涤助剂层状结晶二硅酸钠的技术进展及发展前景

介绍了新一代无磷洗涤助洗荆——层状结晶二硅酸钠的性能、技术进展情况,并对今后层状结晶二硅酸钠的发展提出了自己的见解。     

Environmental value chain management of laundry detergents in the use phase

Environmental value chain management is concerned with the environmental aspects of products and services along the whole value chain, from raw material and energy acquisition to waste management. The use phase in the value chain remains an understudied subject, despite considerable consumption‐related environmental impacts. The purpose of this paper is to analyse the use phase of laundry detergents in households. Our empirical data consist of interviews in the laundry rooms of 299 Finnish households. Consumers’ environmental awareness, use of dosage measuring devices and actual doses of laundry detergents are studied in the empirical part of the study. The results show that consumers do not perceive households as significant polluters, the measuring devices they use are diverse and the number of ‘heavy users’ is high in all detergent brands. It is concluded that in the consumption of laundry detergents, consumers do not perceive environmental issues as specific value criteria in relation to the use of laundry detergents. Manufacturers, marketers and other actors in the value chain of laundry detergents could contribute to alleviating the harmful environmental impacts of the use phase by more effective consumer education and better product design. For consumers, it might be beneficial to adopt eco‐efficiency thinking in their daily consumption.     

Openness and Industrial Response in a Wal‐Mart World: A Case Study of Mexican Soaps,Detergents and Surfactant Producers

This paper uses a case study approach to explore the effects of NAFTA and GATT membership on innovation and trade in the Mexican soaps, detergents and surfactants (SDS) industry. Several basic findings emerge. First, the most fundamental effect of NAFTA and the GATT on the SDS industry was to help induce Wal‐Mart to enter Mexico. Once there, Walmex fundamentally changed the retail sector, forcing SDS firms to cut their profit margins and/or innovate. Those unable to respond to this new environment tended to lose market share and, in some cases, disappear altogether. Second, partly in response to Walmex, many Mexican producers logged impressive efficiency gains during the previous decade. These gains came both from labour‐shedding and from innovation, which in turn was fuelled by innovative input suppliers and by multinationals bringing new products and processes from their headquarters to Mexico. Finally, although Mexican detergent exports captured an increasing share of the US detergent market over the past decade, Mexican sales in the US were inhibited by a combination of excessive shipping delays at the border and artificially high input prices (due to Mexican protection of domestic caustic soda suppliers). They were also held back by the major re‐tooling costs that Mexican producers would have had to incur in order to establish brand recognition among non‐Latin consumers, and in order to comply with zero phosphate laws in many regions of the US.     

进出口含钙元素类商品归类化验关键点分析

进出口含钙元素类商品的归类需要结合元素、物相成分、工艺过程,物理指标等多项指标进行分析。重质碳酸钙、沉淀碳酸钙和改性碳酸钙商品的外观和成分通常无明显差异,硝酸铵钙类商品在进出口税则中没有相关描述,此类商品的准确归类是归类难点。本文对碳酸钙、硝酸钙盐、硝酸铵钙商品的归类化验关键点进行探讨,便于精准化验、准确归类。     

新型肥料的最新开发进展及应用

现代农业正在促使化肥品种结构发生变革，产生质的飞跃，近年来各种新型肥料不断问世。新型肥料的主要作用是能够直接或间接地为作物提供必需的营养成分，调节土壤酸碱度，改良土壤结构，改善土壤理化性质和生物学性质，调节或改善作物的生长机制，改善肥料品质和性质及提高肥料的利用率。21世纪以后，中国新型肥料研发和推广使用正快速发展，肥料结构不断优化，新型肥料更是异军突起。介绍了近期中国最新创制的活化磷肥、有机钾肥、氨酸螯合肥、含肽氮肥、硫磺加强型肥料、富过磷酸钙磷肥、生物有机肥、高分子聚合物增效肥料等8种新型肥料的开发进展和应用概况。．