微电流电解对尿素降解的机理及影响因素研究

采用微电流电解技术对模拟游泳池水中的尿素进行降解处理,探索了电解对尿素的去除机理,研究了电流密度和氯离子浓度等因素对电解去除尿素效果的影响。结果表明:以钌钛和不锈钢分别做阳极和阴极材料,当水溶液中有较高浓度的氯离子存在时,电解过程中产生的活性氯使得尿素被氧化,尿素降解产物中无氨氮、氯胺等二次污染物,尿素极有可能通过电解生成了N2等气体挥发到空气中。电流密度和氯离子浓度对尿素的去除效率有很大影响,随着电流密度和氯离子浓度的增加,尿素去除效率逐渐上升。在500 mg/L的氯离子浓度条件下,电流密度为12 m A/cm2时,电解处理30 min时尿素去除率可达99.5%。将微电流电解技术应用于游泳池水中的尿素去除,无需添加电解质,即能达到较高的尿素去除效果,采用该技术对游泳池水中的尿素进行降解去除完全可行。     

Water quality in the southern Tibetan Plateau: chemical evaluation of the Yarlung Tsangpo (Brahmaputra)

Yarlung Tsangpo (Brahmaputra) is the largest river system draining the northern slopes of the Himalayan ranges on the southern Tibetan Plateau. It remains one of only two large non‐regulated rivers in China. In this paper the chemical composition of Yarlung Tsangpo and its major tributaries (Raga Tsangpo, Nyangchu and Lhasa River) are studied. Water samples (n = 55) were collected and measured for major ions, trace elements and nutrients in order to: (1) define the present chemical quality of this water course; (2) address possible mechanisms governing the water chemical compositions, and (3) identify potential sources for contaminants. Multivariable analysis shows that geology and climate are the major explanatory variables for the spatial variation in water chemistry in this river system. In general, water chemistry is mainly controlled by carbonate weathering, with Ca²⁺ and HCO being the dominant ions. In addition, runoff from brackish/saline lakes and geothermal waters, enriched in Na⁺, Cl^?, SO, Mg²⁺ and Li, are major contributors of elevated concentrations of these solutes in the headwater regions resulting in a relatively high loading of total dissolved solids (TDS, 146–397 mg L^?1). Levels of most heavy metals and total dissolved nutrients were generally found to be low. However, elevated As concentration (avg. 95 μg L^?1) in the headwaters and additions from untreated wastewater were evident at some locations. Copyright © 2009 John Wiley & Sons, Ltd.     

浅析人民币升值对广州市加工贸易出口的影响及对策

从人民币升值的大背景入手,对广州2005至2008年市加工贸易出口特点进行分析,以人民币汇率升值对广州市对外贸易的正反影响为例,从政府干预及政策支持和加工贸易出口企业的角度,提出广州加工贸易出口对应人民币升值的对策.     

On the forecastability of share prices on the Viennese stock exchange

In this paper the Viennese stock exchange data are analysed by using ARMA and GARCH technology. After using AIC and BIC for estimating the linear structure of the time series, to the resulting innovations a GARCH(1,1) model is fit. The resulting residuals are then tested for serial independence and constancy of its distribution to check whether the models are reasonable. Main result is that the residuals of this ARMA-GARCH(1,1)-model are reasonably iid (which is checked by BDS and classical independence tests) for index data and significantly less well-behaved for stock data. Second, there is considerable autocorrelation in the data (especially in the Viennese indices WBK and ATX) which can be exploited even with 1.25% transaction costs (which is checked by a posteriori analysis of a strategy which exploits an underlying time-varying AR(1) model), however, much higher profit can be made with 0.5% transaction costs. Furthermore, the same techniques are applied to US Standard & Poor 500 index and the results for both data sets are compared giving the result that the US-market looks much more mature than the Viennese one.Financial Support by the Institute for Advanced Studies, Vienna, and the Fonds zur Förderung der wissenschaftlichen Forschung, Vienna, Grant P 9176 is gratefully acknowledged. This paper is a slightly abbreviated version of the Research Report No. 135 by the same authors (see References), which contains many detailed plots of the results.     

Real Exchange Rate and External Balance: How Important Are Price Deflators?

This paper contrasts real effective exchange rate (REER) measures based on different deflators (consumer price index, GDP deflator, and unit labor cost) and discusses potential implications for the link—or lack thereof—between the REER and the external balance. We begin by comparing the evolution of different measures of REER to confirm that the choice of deflator plays a significant role in REER movements. A subsequent empirical investigation based on 35 developed and emerging market economies over 1995–2017 yields comprehensive and robust evidence that only the REER deflated by unit labor cost exhibits contemporaneous patterns consistent with the expenditure-switching mechanism. Finally, we show that a standard open-economy model with nominal rigidities and trade in intermediate goods is able to generate these aforementioned patterns.     

National and International Water Law

Abstract

The exchange of data and information relating to transboundary water resources is widely accepted as being an appropriate starting point for more comprehensive cooperation. This paper examines under what conditions data and information exchange occur in relation to shared water resources, and hence examines when it can be used as a confidence building measure. An overview of several major international river basins together with more detailed case studies of the Mekong. Rio Grande, and Rhine River basins suggest that factors that promote data and information exchange include the presence of compatible needs, absence of legacies of mistrust, increasing water resources stress, perceptions that cooperation is of mutual benefit, external pressure and funding, comparable levels of institutional capacity, popular and political concern about water resources management, and functional formal or informal cooperative arrangements. Analysis of the situation prevailing between Israel and the Palestinians with regard to shared water resources suggests that data and information exchange does not seem likely in the short term, even though other forms of cooperation have been established with mixed results. This suggests that in some situations, at least, data and information exchange relating to shared water resources may not be useful as a first step in establishing more comprehensive cooperation.     

Observation of the induced pressure in a hybrid mlcro/nano-channel

This paper studies the flow characteristics in micro/nano-channels subjected to an applied electric field. The nano-channel flow was observed by means of the fluorescence Calcein. A Fluorescence Concentration Gradient Interface (FCGI) was observed across the nano-channel array. The front of the FCGI was shown to have an analogous parabolic shape. The propagation of this interface reflects indirectly the induced pressure at the micro/nano-channel junction, where the enrichment-depletion processes are known to take place. This induced pressure was predicted by numerical simulations, and this paper gives the first experimental evidence.     

闸后水流运动的SPH法数值模拟

在对光滑离子流体动力学(SPH)法的基本原理、核函数及控制方程离散格式、边界处理方法等进行介绍的基础上建立了数值水槽模型,成功模拟了闸门开启后水流的界面变形、界面破碎、气泡的生成及溃灭,以及涌浪的生成过程。结果表明SPH法能够捕捉到流体的飞溅及融合现象,适于模拟具有瞬时极大变形等水流运动。     

硫酸盐还原菌处理重金属铬离子废水的实验研究

以静态试验的方式,研究了硫酸盐还原菌(SRB)处理不同浓度的重金属铬离子废水,以及研究了对不同浓度铬离子废水处理不同时间后的各自处理效率,从而得到处理效率最佳的初始铬离子浓度和处理时间。结果表明:当铬(Ⅵ)离子废水初始浓度为50 mg/L到100 mg/L时,SRB菌对铬(Ⅵ)离子废水的处理效率最好,达到99.62%和99.74%;并且较为经济的最佳处理时间为1 h。     

乐清湾海洋环境季节特征及水交换过程研究

基于4个航次的实测资料,分析乐清湾的温(度)盐(度)、潮汐、潮流和余流等海洋环境季节分布特征,并采用环境流体动力学模型研究乐清湾的水交换过程,提出一个计算海湾水体平均置换率的简单公式,以直观描述湾内水体与湾外水体交换的过程特征。结果表明,乐清湾的水交换能力与湾内温(度)盐(度)水平及断面分布特征一致,从口门到湾顶,水交换能力差别较大,连屿至打水山断面以南的水体基本1个月可完全交换,连屿至打水山断面以北的水体2个月仍然无法交换到湾口水平。