晶化时间对CoAPO-11分子筛合成过程中转晶的影响

本文研究了晶化时间对低钴含量(x=0.1)的CoAPO-11分子筛合成过程中转晶现象的影响,并采用XRD、SEM对产物进行表征。结果表明,200℃下晶化48 h,可获得纯相CoAPO-11;当晶化时间超过48 h时,产物便开始向[Co-Al-P-O]-GIS型分子筛转化;晶化延长至72 h时,产物已全部转化为[Co-Al-P-O]-GIS型分子筛,该转化过程不可逆。从分子筛骨架结构单元出发,阐述了转晶现象的内在影响因素。     

Is real per capita state personal income stationary? New nonlinear,asymmetric panel-data evidence

This paper re-examines the stochastic properties of U.S. state real per capita personal income, using new panel unit-root procedures. The new developments incorporate non-linearity, asymmetry, and cross-sectional correlation within panel-data estimation. Including nonlinearity and asymmetry finds that 43 states exhibit stationary real per capita personal income whereas including only nonlinearity produces 42 states that exhibit stationarity. Stated differently, we find that two states exhibit nonstationary real per capita personal income when considering nonlinearity, asymmetry, and cross-sectional dependence.     

Varying Coefficient Regression Models: A Review and New Developments

Varying coefficient regression models are known to be very useful tools for analysing the relation between a response and a group of covariates. Their structure and interpretability are similar to those for the traditional linear regression model, but they are more flexible because of the infinite dimensionality of the corresponding parameter spaces. The aims of this paper are to give an overview on the existing methodological and theoretical developments for varying coefficient models and to discuss their extensions with some new developments. The new developments enable us to use different amount of smoothing for estimating different component functions in the models. They are for a flexible form of varying coefficient models that requires smoothing across different covariates' spaces and are based on the smooth backfitting technique that is admitted as a powerful technique for fitting structural regression models and is also known to free us from the curse of dimensionality.     

复合模板剂合成SBA-15介孔分子筛的结构表征及机理研究

采用复合模板剂P123及Tritonx-100合成新型SBA-15介孔分子筛,分别利用N2等温吸附、X射线衍射及透射电镜对样品进行表征。介孔分子筛比表面积可达600 m2/g,单位质量的孔容积大于1 mL/g,平均孔径为7~8 nm,孔径分布窄,孔道长程有序,结晶度较高。通过与单一模板剂合成样品的比较可知,辅助模板剂Tritonx-100能有效地改善孔径分布及孔道排列,通过实验找出了最佳模板剂配比为n(Tritonx-100)∶n(P123)=4∶1。     

基于Shift-Share模型的“镰刀弯”地区食增产结构变动分析——兼论玉米种植结构调整

[目的]"镰刀弯"地区玉米种植面积大幅度增加,粮食种植结构单一,为确保粮食安全稳定、多元化发展,需要明确该地区粮食生产结构中不同作物的变化特点和竞争优势.[方法]文章运用Shift-Share模型对"镰刀弯"地区的粮食作物生产结构和竞争力优势进行比较,分析了水稻、玉米、薯类、豆类以及其他作物的结构和竞争力优势差异.[结果]"镰刀弯"地区内部不同区域之间不同作物的结构优势和竞争力优势差异明显,其主要原因在于不同作物的播种面积和单位面积产量增长变动速度不同.[结论]"镰刀弯"地区粮食种植结构的调整,尤其是玉米种植面积的调减,应当充分考虑不同作物之间的优势差异,在满足可持续发展和市场需求且不形成过度供给的情况下,增加优势作物的种植,最终形成合理的种植结构和区域布局.     

K2O-B2O3-SiO2/Al2O3低温共烧陶瓷介质材料研究

采用1 500℃高温熔融水淬制得K2O-(n-x) B2O3-xSiO2玻璃粉,掺入Al2O3陶瓷填充料来制备K2O-(n-x)B2O3xSiO2/Al2O3低温共烧陶瓷介质材料.系统研究了玻璃基中SiO2/B2O3比例变化和玻璃掺入量对玻璃/陶瓷材料结构和性能的影响规律.研究结果表明,B2O3含量增加抑制了玻璃Y中SiO2析晶,使复合材料的介电常数、介电损耗在一定程度上有所减小,复合材料的抗弯强度也有一定程度的减小.     

论徇私枉法罪主观要件及共犯

徇私枉法罪是司法工作人员渎职犯罪中的一种,在司法实务中虽然不属于多发罪,但对司法公信力的危害极大。目前在该罪构成条件上尚有争议。本文认为,"徇私"、"徇情"并非只是一个概念,而是需要查证的具体事项;在内外勾结案件中,司法人员应起主要作用。     

浅析新型分子筛材料的性能及检验方法—4A分子筛的标准化

4A分子筛作为一种新型材料,具有很好的吸附、分离、分散等性能,广泛应用于化工、涂料、日化、汽车及现代医学等领域。由于涉及领域较多,新修订的HG／T2524—2010《4A分子筛》标准在使用过程中可能会遇到一些问题。本文对该标准进行了解读与介绍,包括主要技术性能和检验方法,可以帮助各领域标准应用者正确运用标准,以达到预期目的。     

医用分子筛中心制氧系统管理的相关法律法规应用探讨

本文从医用分子筛中心制氧系统的原理、特殊性和风险性的角度出发,阐述了医用分子筛中心制氧系统依法管理的重要性,概述了医用分子筛中心制氧系统管理相关的各类法律法规,并论述了其与医疗设备全过程管理各阶段的重点相关部分。     

Efficient estimation of semiparametric conditional moment models with possibly nonsmooth residuals

This paper considers semiparametric efficient estimation of conditional moment models with possibly nonsmooth residuals in unknown parametric components (θ) and unknown functions (h) of endogenous variables. We show that: (1) the penalized sieve minimum distance (PSMD) estimator can simultaneously achieve root-n asymptotic normality of and nonparametric optimal convergence rate of , allowing for noncompact function parameter spaces; (2) a simple weighted bootstrap procedure consistently estimates the limiting distribution of the PSMD ; (3) the semiparametric efficiency bound formula of [Ai, C., Chen, X., 2003. Efficient estimation of models with conditional moment restrictions containing unknown functions. Econometrica, 71, 1795–1843] remains valid for conditional models with nonsmooth residuals, and the optimally weighted PSMD estimator achieves the bound; (4) the centered, profiled optimally weighted PSMD criterion is asymptotically chi-square distributed. We illustrate our theories using a partially linear quantile instrumental variables (IV) regression, a Monte Carlo study, and an empirical estimation of the shape-invariant quantile IV Engel curves.