Simulation of water and nitrogen dynamics in soils during wastewater applications by using a finite-element model

A mathematical model was developed to simulate water movement, mass transport, and nitrogen transformations in soils during wastewater applications. The model is one-dimensional and based on the Galerkin finite-element method. The submodel of mass transport of nitrogen incorporates the convection-dispersion processes of ammonium and nitrate nitrogen, nitrification, denitrification, ammonium exchange and uptake of ammonium and nitrate ions. The accuracy and validity of the proposed model was examined by comparison with an explicit-implicit finite-difference model results. The model was used for simulation of water and nitrogen dynamics during wastewater application in homogeneous and multi-layered soils under different N concentration, rate, duration and scheduling of application.     

Prevention versus Treatment under Precautionary Regulation: A Case Study of Groundwater Contamination under Uncertainty

Policy discussions on agricultural pollution problems characterize prevention as more cost effective and precautionary than ex post treatment. We derive conditions under which treatment alone is more cost effective in situations involving multiple sources of emissions, multiple sites affected, and a commonly used precautionary approach to uncertainty. We also show that a greater degree of precaution can result in less reliance on prevention. An empirical case study indicates that treatment alone is the most cost-effective means of dealing with nitrate in most Maryland community water system wells. The use of leaching prevention measures is restricted to the most intensive poultry producing areas. The incremental cost of precaution is substantial.     

Stochastic Technology, Risk Preferences, and Adoption of Site-Specific Technologies

A model of farmer decision making is developed to determine the extent to which uncertainties about soil fertility and weather affect the value of site-specific technologies (SSTs) using jointly estimated risk and technology parameters. Uncertainty can lead risk-averse farmers to apply more fertilizers and generate more pollution than in the certainty case. Ignoring uncertainty and risk aversion would overestimate the economic and environmental benefits of SSTs and underestimate the subsidy required to induce adoption. Accounting for uncertainties and risk preferences might explain the low observed adoption rates of SSTs. Improving the accuracy of SSTs would increase the incentives for adoption.     

小氮肥清洁生产实践

文章介绍了沅江市氮肥厂废水闭路循环、尾气回收、废渣综合利用等工程,并介绍了该厂的生产工艺、污染源分布及排污特点。     

纯氧曝气的研究进展

介绍了纯氧曝气的生化机理、应用领域、供氧方式、污泥性能等以及它与普通空气曝气相比在技术、经济方面显示出的优越性。随着纯氧曝气的发展和国家新标准增加了脱氮除磷方面的排放要求，使得纯氧曝气在城市污水处理老厂的改造和新厂的建设中具有很好的前昔。     

Consequences of different cutting regimes on regrowth and nutrient stoichiometry of Sparganium erectum L. and Potamogeton natans L.

Aquatic vegetation forms an essential component in freshwater ecosystems but due to changed environmental and anthropogenic conditions often needs management to reduce nuisance for human land‐use. In this paper, the authors looked at the regrowth of two macrophyte species (Potamogeton natans and Sparganium erectum) in two lowland rivers under different cutting treatments. After an initial cross‐sectional transect was manually removed from bank to bank at the beginning of the growth season, a monthly repetitive removal of biomass in plots on that transect was done during the rest of the growth season (testing frequency of mowing). Additional new transects were also cut in subsequent months (testing timing of mowing). Finally, biomass was repetitively removed in plots in those additional transects too (testing frequency of mowing × timing of mowing). The biomass at the end of the growth season was analysed for C, N, P, and Si. It was demonstrated that timing and frequency of vegetation cutting has an important effect on the capacity and rate of species' recovery and therefore on the efficiency of the applied management. Nutrient stoichiometry of the regrown biomass was directly affected by cutting. Caused by differences in the applied timing and frequency of the cutting, C/N and N/P ratios and BSi concentrations were highly variable. Yet, overall, there was a clear tendency towards a higher C/N ratio and BSi concentration and lower N/P ratio in biomass that recovered after cutting. This human impact on the quantity and quality of autochthonous organic matter may have knock‐on effects on the decomposers food web and mineralization process.     

考虑大气沉降的湖库分区动态水环境容量精细解析

针对面源污染为主的湖库型流域,为建立水质目标管理与污染总量控制之间更精准的响应关系,借鉴日最大负荷总量模式,基于物质量平衡原理提出考虑径流丰枯变化、不均匀混合、大气沉降等影响因素的湖库分区动态水环境容量精细解析方法,包括污染混合区设置、代表水文系列确定、逐日分区水量水质计算。以沙河水库为例,分别以全湖Ⅱ类、主湖Ⅱ类作为水质管理目标,采用2010—2015年代表水文系列对总氮动态水环境容量进行精细解析。结果表明：全湖Ⅱ类、主湖Ⅱ类水质管理目标下沙河水库总氮水环境容量的多年均值分别为36.7 t和99.43 t,若不考虑湖滨混合区,全湖Ⅱ类水质目标下总氮的年水环境容量计算值偏大66.43%;实施水质目标管理的水域面积越大,大气沉降对水环境容量的影响越大;径流年际及年内丰枯变化对水环境容量的影响显著;各分区总氮控制总量占全流域总量的比例与面积比基本一致。湖库分区动态水环境容量精细解析可量化不同因素对水环境容量计算结果的影响,科学解析面源输入型湖库水环境容量的时空结构特征,实现水质目标管理与污染总量分区管控的有机联动,更好地支撑流域水环境的精细化管理。     

稻草强化生物膜浮床脱除工业尾水中氮素及COD的效果

工业污水处理厂排放的尾水中总氮含量偏高,容易引起地表水体的富营养化。为了提高尾水中总氮的去除效率,通过模拟稳定塘静态和动态试验,对比了不同稻草添加量(0,0.18,0.54 g/L)强化生物膜浮床脱除工业尾水中总氮(TN)的效果。静态试验结果表明:随着稻草量的增加,TN的去除率显著提高;10 d后,添加0(CK)、0.18 g/L(T1)和0.54 g/L(T2)稻草的尾水中,TN去除率分别为18%,40%,93%。动态试验结果显示,水力停留时间(HRT)为 4 d时,CK、T1和T2的平均TN去除率分别为10%,22%,49%,且3种情况下的进出水COD浓度无显著差异。这主要是由于稻草通过缓慢释放碳源为生物膜中异养反硝化细菌提供可利用的有机物。研究成果可为工业尾水深度处理脱氮技术提供参考。     

生物慢滤系统对再生水中氮磷降解的试验研究

利用生物慢滤系统中菌-藻共生的特点,对用于景观补水的再生水中氮磷进行有效的去除,可有效预防由于再生水中氮磷营养盐浓度较高而引发的景观水体富营养化问题。通过生物慢滤系统净化再生水的试验研究表明,生物慢滤系统在保持上覆水深为80cm、滤层厚度为80cm、滤速为0.1m/h的条件下,对水体中总氮、氨氮、硝酸盐氮、总磷和高锰酸盐指数平均去除率分别为57.55%、50.16%、46.37%、66.32%和47.04%,叶绿素a的去除率可达95.75%;经生物慢滤系统处理后的再生水在景观储存过程中藻类的生长缓慢,叶绿素a含量始终维持在较低水平,氮磷含量较低且趋于稳定。经生物慢滤池处理的再生水用于景观水体的补充水源,可减少富营养化的发生频率。     

铜电极表面硝酸盐电化学还原机理研究

目前地表水受到严重氮污染,其中以离子态硝酸盐为主。实验利用线性扫描伏安法与恒电位电解法,研究了铜电极表面硝酸盐电化学还原产物与反应机理。结果表明,硝酸盐的还原产物取决于外加电位。铜电极上硝酸盐的吸附从-0.6 V(以汞/氧化汞电极为参比)开始,-0.8~-1.0 V之间硝酸盐还原为亚硝酸盐,该反应为整个硝酸盐还原过程的速控步骤;理想产物氮气主要在-1.0~-1.2 V之间生成;-1.2~-1.4 V之间主要还原产物为氨氮。随着电势降低,反应速率增大,对副产物氨氮的选择性也升高。