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酸性加压浸出液中钼的萃取分离
引用本文:邹小平,张邦胜,张 磊,等.酸性加压浸出液中钼的萃取分离[J].中国资源综合利用,2014(4):13-16.
作者姓名:邹小平  张邦胜  张 磊  
作者单位:[1]东北大学,沈阳110819 [2]北京矿冶研究总院,北京100160
基金项目:基金项目:国家863计划项目(2013AA064005).
摘    要:研究了从酸性加压浸出液中采用溶剂萃取法提取钼工艺,考察了萃取剂浓度、改质剂浓度、萃取相比、萃取时间等对钼萃取率的影响。试验结果表明,在有机相组成25%N235+5%异辛醇+磺化煤油,O/A=3/1,混合时间3min的条件下,钼的萃取率可达到98%以上;负栽有机相采用20%的氨水反萃,O/A=1/3.在两级逆流萃取的条件下钼反萃率超过98%。

关 键 词:钼精矿    加压浸出  萃取

Molybdenum Solvent Extraction Technology From Acid Pressure Leaching Solution
Zou Xiaoping,Zhang Bangsheng,Zhang Lei,Wang Haibei.Molybdenum Solvent Extraction Technology From Acid Pressure Leaching Solution[J].China Resources Comprehensive Utilization,2014(4):13-16.
Authors:Zou Xiaoping  Zhang Bangsheng  Zhang Lei  Wang Haibei
Institution:1.Northeastern University, Shenyang 110004, China; 2.Beijing General Research Institute of Mining and Metallurgy, Beijing 100160)
Abstract:The technology of extracting molybodenum from acid pressure leaching solution adopting solvent extraction method was researched. The effects of extractant concentration, modification agent concentration, phase ratio and extraction time on the extraction rate of Mo were investigated. The tests result showed that the extraction ratio of Mo could reach above 98% at the condition of the organic phase containing 20% N235, 5%Isooctanol and Kerosene with O/A of 1/3, and the mixing time of 3 rain. When the loaded organic reagent was stripped with 20% ammonia, the stripping ratio of Mo was more than 98% after two-stage stripping with O/A of 3/1.
Keywords:molybdenum concentrate  molybdenum  pressure leaching  extraction
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