| 浊点萃取-火焰原子吸收光谱法测定煤质活性炭中镉含量 |
| |
| 引用本文： | 杨蒲晨,赵发宝,张鑫鑫. 浊点萃取-火焰原子吸收光谱法测定煤质活性炭中镉含量[J]. 检验检疫科学, 2014, 0(2): 15-17 |
| |
| 作者姓名： | 杨蒲晨 赵发宝 张鑫鑫 |
| |
| 作者单位： | [1]大同出入境检验检疫局,山西大同037006 [2]山西出入境检验检疫局 ,山西大同037006 [3]长治出入境检验检疫局,山西大同037006 |
| |
| 摘 要： | 煤质活性炭样品在微波消解仪中进行消解，采取浊点萃取进行处理，将待测元素有效收集，用火焰原子吸收光谱仪进行测定。试验中采取双硫腙为络合剂，以非离子型表面活性剂Triton X-100为萃取剂，选取测试效果最佳的元素分析谱线，优化原子吸收分析条件，采用基体匹配法消除其他元素的干扰，测定镉的检出限为0.003μg/mL。此方法用于分析煤质活性炭试样中镉含量，结果的相对标准偏差（n=6）为0.71%，回收率为103%。
|
| 关 键 词： | 火焰原子吸收光谱仪 浊点萃取 煤质活性炭 镉 |
FAAS Determination of Cadmium in Activated Carbon from Coal after Cloud Point Extraction |
| |
| Yang Puchen,Zhao Fabao,Zhang Xinxin. FAAS Determination of Cadmium in Activated Carbon from Coal after Cloud Point Extraction[J]. Inspection and Quarantine Science, 2014, 0(2): 15-17 |
| |
| Authors: | Yang Puchen Zhao Fabao Zhang Xinxin |
| |
| Affiliation: | 1.Datong Entry-Exit Inspection and Quarantine Bureau, Datong, Shanxi, 037006; 2.Shanxi Entry-Exit Inspection and Quarantine Bureau; 3.Changzhi Entry-Exit Inspection and Quarantine Bureau) |
| |
| Abstract: | The activated carbon sample digested by microwave digestion, taking the cloud point extraction for processing, effectively collected the element under test,, the test solutions were determined by FAAS. Using dithizone as complexing agent and Triton X-100 non-ionic surface active agent as the extractant, selecting optimal test line for element analysis, optimizing the conditions of FAAS, using the matrix matching method to eliminate the interference of other elements, the detection limit was 0.003μg/mL. The values of RSD＆#39;s （n=6） was 0.71%, and recovery, 103%for this method respectively. |
| |
| Keywords: | FAAS Cloud Point Extraction Activated Carbon from Coal Cadmium |
| 本文献已被 维普 等数据库收录！ |
|
