| 高效液相色谱法和高效液相色谱-质谱/质谱法测定荔枝中对氯苯氧乙酸（钠） |
| |
| 引用本文： | 钟莉萍,徐敦明,方恩华,张志刚,陈鹭平,林立毅,周昱. 高效液相色谱法和高效液相色谱-质谱/质谱法测定荔枝中对氯苯氧乙酸（钠）[J]. 检验检疫科学, 2010, 20(2): 24-27 |
| |
| 作者姓名： | 钟莉萍 徐敦明 方恩华 张志刚 陈鹭平 林立毅 周昱 |
| |
| 作者单位： | 厦门出入境检验检疫局,福建厦门,361026 |
| |
| 基金项目： | 福建省自然基金青年创新项目，国家质检总局科技项目，厦门市科技计划项目 |
| |
| 摘 要： | 建立了荔枝中对氯苯氧乙酸（钠）残留量的液相色谱和液相-串联质谱检测方法,采用碱性水提取,利用二氯甲烷液液萃取进行净化,用液相色谱方法在280 nm检测,检出限为0.02 mg/kg。在负离子模式下进行液质串联质谱检测,检出限为0.01 mg/kg。本方法的添加回收率在78.2%～106.7%,变异系数为2.0%～12.2%。回收率、检测限等技术参数均能满足相关检测要求。本方法应用于65个实验样品的检测,其中有两个样品为阳性,含量分别为0.032 mg/kg及0.026 mg/kg。
|
| 关 键 词： | 对氯苯氧乙酸钠 液相色谱法 液相-串联质谱法 |
Determination of(Sodium) Parachlorophenoxy Acetate in Lichee by High-Performance Liquid Chromatography and Liquid Chromatography/Tandem Mass Spectrometry |
| |
| Zhong Liping,Xu Dunming,Fang Enhua,Zhang Zhigang,Chen Luping,Lin Liyi,Zhou Yu. Determination of(Sodium) Parachlorophenoxy Acetate in Lichee by High-Performance Liquid Chromatography and Liquid Chromatography/Tandem Mass Spectrometry[J]. Inspection and Quarantine Science, 2010, 20(2): 24-27 |
| |
| Authors: | Zhong Liping Xu Dunming Fang Enhua Zhang Zhigang Chen Luping Lin Liyi Zhou Yu |
| |
| Affiliation: | Zhong Liping,Xu Dunming,Fang Enhua,Zhang Zhigang,Chen Luping,Lin Liyi,Zhou Yu(Xiamen Entry-Exit Inspection , Quarantine Bureau,Xiamen,Fujian,361026) |
| |
| Abstract: | A sensitive and selective analytical method for the determination of(sodium) parachlorophenoxy acetate(sodium 4-CPA) in lichee by high-performance liquid chromatography(HPLC) and liquid chromatography/tandem mass spectrometry(LC-MS/MS) was developed.The sample was extracted with water(pH 10) and the extract was cleaned up with dichloromethane.The LOQs were 0.02 and 0.01 mg/kg for HPLC and LC-MS/MS,respectively.The RSDs of recovery for indoxacarb were 2.0 %-12.2 % in lichee.Six repetitive determinations of r... |
| |
| Keywords: | (Sodium) parachlorophenoxy Acetate High-Performance Liquid Chromatography(HPLC) Liquid Chromatography/Tandem Mass Spectrometry(LC-MS/MS) |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
