4-(二(2-二乙基二硫代氨基甲酸酯基))胺基苯甲醛的合成、表征和螯合性能 |
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引用本文: | 张勇,;叶聪,;张顺林,;秦训浩,;高晓娜,;陈雪梅.4-(二(2-二乙基二硫代氨基甲酸酯基))胺基苯甲醛的合成、表征和螯合性能[J].黄石理工学院学报,2014(4):41-45. |
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作者姓名: | 张勇 ;叶聪 ;张顺林 ;秦训浩 ;高晓娜 ;陈雪梅 |
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作者单位: | [1]湖北理工学院化学与材料工程学院,湖北黄石435003; [2]湖北理工学院矿区环境污染控制与修复湖北省重点实验室,湖北黄石435003 |
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基金项目: | 湖北省教育厅青年人才项目(项目编号:Q20134402);湖北理工学院校级科研项目(项目编号:12xjz21C);矿区环境污染控制与修复湖北省重点实验室基金项目(项目编号:2012103). |
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摘 要: | 以铜试剂等为反应原料合成了4-(二(2-二乙基二硫代氨基甲酸酯基))胺基苯甲醛(ZY3),通过X-射线单晶衍射对其晶体结构进行了表征,并且研究了它的螯合性能。研究结果表明:ZY3属于单斜晶系,空间群为P2(1)/n。它与重金属离子有很强的配位作用,与Cu2+的络合比例为1∶1,可通过分光光度法检测微量Cu2+。
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关 键 词: | 螯合剂 合成 晶体结构 螯合性能 |
Synthesis,Crystal Structure and Chelating Property of (4-formylphenylazanediyl) -bis-(ethane-2,1-diyl) -bis-diethyl-carbamodithioate |
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Institution: | Zhang Yong, Ye Cong, Zhang Shunlin, Qin Xunhao, Gao Xiaona, Chen Xuemei (1School of Chemical and Materials Engineering,Hubei Polytechnic University,Huangshi Hubei 435033;2Hubei Key Laboratory of Mine Environmental Pollution Control & Remediation,Hubei Polytechnic University,Huangshi Hubei 435003) |
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Abstract: | (4 -Formylphenylazanediyl) -bis -(ethane -2,1 -diyl) -bis -diethyl -carbamodithioate (ZY3) has been synthesized by the materials of copper reagent,etc.The crystal structure of ZY3 was deter-mined by single crystal X -ray diffraction ,and its chelating property was also investigated .The results showed that the ZY3 belonged to monoclinic system,space group,P2(1)/n.It had very strong coordinating ability with heavy metal ions,the stoichiometry of Cu2+and ZY3 was estimated to be 1∶1,and it can detect trace Cu2+by spectrophotometry. |
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Keywords: | chelator synthesis crystal structure chelating property |
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