| 丙烯直接氧化制环氧丙烷的清洁生产技术 |
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| 引用本文： | 张利粉.丙烯直接氧化制环氧丙烷的清洁生产技术[J].化工科技市场,2010,33(6):34-37. |
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| 作者姓名： | 张利粉 |
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| 作者单位： | 辽阳石化公司研究院,辽宁辽阳,111003 |
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| 摘 要： | 指出了氯醇法和共氧化法的发展趋势,概述了丙烯催化环氧化合成环氧丙烷技术的研究进展,包括以分子氧、H2O2、原位合成H2O2和有机过氧化物为氧化剂的催化氧化法。同时对各种催化反应工艺、催化剂和催化反应机理进行了讨论,并对PO清洁生产技术的前景进行了展望。
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| 关 键 词： | 丙烯 环氧丙烷 环氧化 催化剂 |
Clean production technology of propylene oxide preparation by propylene epoxidation |
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| Zhang Li-fen.Clean production technology of propylene oxide preparation by propylene epoxidation[J].Chemical Technology Market,2010,33(6):34-37. |
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| Authors: | Zhang Li-fen |
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| Institution: | Zhang Lifen(Liaoyang Petrochemical Company Research Institute,Liaoyang 111003,China) |
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| Abstract: | Development trend of chlorohydrins method and co-oxidation method were pointed out.Research progress in technology of propylene catalytic epoxidation for propylene oxide was reviewed,in which O2,H2O2,in-situ H2O2,and organic peroxide were used as oxidants.Catalytic reaction processes,catalysts,and catalytic reaction mechanisms were discussed.Prospect of clean production technology of propylene oxide was also forecasted. |
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| Keywords: | propylene propylene oxide epoxidation catalytic |
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